If 10.8g of silver is deposited in a silver coulometer connected in series with a copper coulometer, the volue of oxygen liberated is
A. 0.56 dm^3
B. 5.60 dm^3
C. 11.20 dm^3
D. 22.40 dm^3
Using Faraday’s laws of electrolysis:
Step 1: Moles of silver deposited
Reaction at silver coulometer:
{Ag}^+ + e^- 一>{Ag}
Molar mass of Ag = 108 g mol⁻¹
Moles of Ag = {10.8}/{108} = 0.10 mol
So, 0.10 mol of electrons flowed through the circuit.
Step 2: Relation to oxygen liberated
At the anode (oxygen liberation):
4e^- 一>O2
Moles of O2 = {0.10}/{4} = 0.025 mol
Step 3: Volume of oxygen at STP
1 mol of gas = 22.4 { dm}^3
{Volume of O}_2 = 0.025 * 22.4 = 0.56 dm³
✅ Correct Answer
A. 0.56 dm³
PQN:22
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