25.00cm^3 of sodium trioxocarbonate (IV) solution neutralizes 22.50cm^3 of 0.05moldm^-3 hydrochloric acid. Calculate the concentration of Na2CO3.
A. 0.023
B. 0.046
C. 0.230
D. 0.460
Calculation:
CA VA}/{CB VB} = nA/nB
Where:
(CA, VA) → concentration & volume of acid
(CB, VB) → concentration & volume of base
(nA:nB) → ratio from the balanced equation
Step 1: Write the balanced equation
Na2CO3 + 2HCl一> 2NaCl + H2O + CO2
Ratio (nA:nB = 1:2)
(1 mole Na₂CO₃ reacts with 2 moles HCl)
Step 2: Apply the formula
{{C{Na₂CO₃} * V{Na₂CO₃}}/{C{HCl} *V{HCl}} = {1}/{2}
Plug in the values:
{C{Na₂CO₃} * 25.00}/{0.05 *22.50} = {1}/{2}
Convert cm³ to same units (they cancel if both in cm³).
C{Na₂CO₃} * 25 = 0.05 * 22.5 * {1}/{2}
C{Na₂CO₃} * 25 = 0.5625
C{Na₂CO₃} = {0.5625}/{25} = 0.0225 approx 0.023 mol/dm³
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